ALKYLATION OF [PT2(µ-S)2(PPH3)4] WITH BORONIC ACID DERIVATIVES BY PRESSURIZED SAMPLE INFUSION ELECTROSPRAY IONIZATION MASS SPECTROMETRY (PSI- ESI-MS) TECHNIQUE
ABSTRACT This project work present the alkylating reaction of with boronic acid alkylating agents.The reactivity of the metalloligand with the boron-functionalized alkylating agents BrCH2(C6H4)B(OR)2 (R = H or C(CH3)2) was investigated by electrospray ionization mass spectrometry (ESI-MS) in real time using the pressurized sample infusion (PSI). The macroscopic reaction of with one mole equivalent of alkylating agents BrCH2(C6H4)B{OC(CH3)2}2and BrCH2(C6H4)B(OH)2 gave the dinuclear monocationic µ-sulfide thiolate complexes + and . ...
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